Table 3. Metal Adsorption Accommodation of Coarse Grafted Metal Adsorbent with the PZ-DTC Accumulation by Batchwise Adsorption Tests Application Single-Metal-Ion Aqueous Solution
Table 4. Metal Adsorption Accommodation and Metal Ion Selectivity of Coarse Grafted Metal Adsorbent with the PZ-DTC Accumulation by Batchwise Adsorption Tests Application Bifold Alloyed Metal Ion Aqueous Solution
Table 5. Cu2 Adsorption Accommodation of Assorted Coarse Grafted Metal Adsorbents beneath Awful Acrid Action (pH 15)
Meanwhile, in the case of the metal adsorbent with chelating anatomic groups such as PZ-DTC, IDA, EDA, and IDE groups, although anniversary chelate-type adsorbent could selectively adsorb Cu2 alike from a high-concentration Na aqueous band-aid at pH 15, the Cu2 adsorption capacities assorted essentially depending on the blazon of chelate groups. The IDA- and EDA-type adsorbents could selectively abolish a trace bulk of Cu2 , which was attenuated in a high-concentration Na aqueous band-aid at pH 15. The Cu2 adsorption capacities per gram of the IDA- and EDA-type adsorbents beneath a awful acrid action (pH 15) were 0.082 and 0.128 mmol-Cu2 /g-adsorbent, respectively. In addition, the Cu2 adsorption accommodation of the IDE-type adsorbent, which was acclimated to apple-pie the awful acrid carving aqueous band-aid of Si dent and apparent the accomplished achievement in a antecedent study, at pH 15, was about 0.314 mmol-Cu2 /g-adsorbent. The acumen for these lower Cu2 adsorption capacities was advised to be that the basic atoms of IDA, EDA, and IDE groups independent oxygen and nitrogen atoms, which display a aerial affection for Na . Therefore, it is advised that assorted chelate groups such as IDA, EDA, and IDE groups could adsorb Cu2 and Na simultaneously.
Meanwhile, in the case of the PZ-DTC-type adsorbent, the Cu2 adsorption accommodation at pH 15 bigger dramatically, attaining 0.754 mmol-Cu2 /g-adsorbent. This was about 2.4 times college than that of the IDE-type adsorbent, which had been the accomplished akin until then. The acumen for this college Cu2 adsorption accommodation was advised to be that the basic atom of the PZ-DTC accumulation did not accommodate an oxygen atom (which exhibits a aerial affection for Na ) and independent a sulfur atom (which exhibits a low affection for Na ). Therefore, it is advised that the PZ-DTC groups could preferentially adsorb Cu2 while excluding Na . Additionally, apropos the adherence of the adsorbent at pH 15, the PZ-DTC-type adsorbent was not physically destroyed and the alien PZ-DTC groups were not appear from the adsorbent, alike afterwards actuality absorbed in the awful acrid band-aid at pH 15 for 1 week.
The aloft after-effects appear that the coarse grafted metal adsorbent with the PZ-DTC accumulation did not lose its metal adsorption action alike beneath a awful acrid action (pH 15). In addition, it was empiric that the PZ-DTC-type adsorbent could balance Cu2 calmly and selectively from a high-concentration Na aqueous band-aid at pH 15.
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